Chapter Outline

16.1 The Basic Principle - Stabilization of the Transition State

16.2 Enzymes Provide Enormous Rate Accelerations
16.3 The Binding Energy of ES Is Crucial to Catalysis

16.4 Entrophy Loss and Destablization of the ES Complex

 

16.5 Transistion-State Analogs Bind Very Tightly to the Active Site

 

16.6 Covalent Catalysis

 

16.7 General Acid-Base Catalysis

 

16.8 Metal Ion Catalysis

 

16.9 Proximity

 

16.10 Typical Enzyme Mechanisms

 

16.11 Serine Proteases

 

16.12 The Aspartic Proteases

 

16.13 Lysozyme

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